A neutron star is a compact stellar object where nuclear physics play an important role. This is particularly the case of the inner crust of neutron stars, composed of a lattice of nuclear clusters immersed in a superfluid neutron gas. Such a system is similar to mettalic clusters present on earth and requires the developpement of a band theory. In the first part of my talk, I will discuss band theory and the Wigner-Seitz approximation. Then I will discuss how the nuclear clusters affect the superfluid and the cooling time of the inner crust. The inner crust matter is treated in the Wigner-Seitz approximation and the pairing properties are calculated in the framework of Hartree-Fock-Bogoliubov approach.